![]() Chiral cyclopentadienyl ligands: design, syntheses and applications in asymmetric catalysis. Light-induced gold-catalyzed Hiyama arylation: a coupling access to biarylboronates. Visible-light-promoted iron-catalyzed C(sp 2)–C(sp 3) Kumada cross-coupling in flow. Photoinduced palladium-catalyzed Negishi cross-couplings enabled by the visible-light absorption of palladium-zinc complexes. Visible-light-induced nickel-catalyzed Negishi cross-couplings by exogenous-photosensitizer-free photocatalysis. ![]() Visible light induced rhodium(I)-catalyzed C–H borylation. Photoinduced ligand-to-metal charge transfer enables photocatalyst-independent light-gated activation of Co(II). Reactivity of transition-metal complexes in excited states: C–O bond coupling reductive elimination of a Ni(II) complex is elicited by the metal-to-ligand charge transfer state. Photoinduced ruthenium-catalyzed alkyl-alkyl cross-coupling reactions. meta-Selective C–H activation of arenes at room temperature using visible light: dual-function ruthenium catalysis. Visible-light-enabled ruthenium-catalyzed meta-C-H alkylation at room temperature. Gandeepan, P., Koeller, J., Korvorapun, K., Mohr, J. Substrate-rhodium cooperativity in photoinduced ortho-alkynylation of arenes. Visible-light-activated asymmetric β-C-H functionalization of acceptor-substituted ketones with 1,2-dicarbonyl compounds. Long-lived charge-transfer states of nickel(II) aryl halide complexes facilitate bimolecular photoinduced electron transfer. The photophysics of photoredox catalysis: a roadmap for catalyst design. Ligand to metal charge transfer transitions in Ru(III) and Os(III) complexes of substituted 2,2’-bipyridines. Photoreactivity of metal-to-ligand charge transfer excited states. Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis. The merger of transition metal and photocatalysis. Alkyl carbon–carbon bond formation by nickel/photoredox cross-coupling. ![]() When metal-catalyzed C–H functionalization meets visible-light photocatalysis. Visible-light-induced, single-metal-catalyzed, directed C–H functionalization: metal-substrate-bound complexes as light-harvesting agents. Visible light-induced transition metal-catalyzed transformations: beyond conventional photosensitizers. Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives. Visible light-induced transition metal catalysis. Thus, the SFI-Rh(I) catalysts extend the scope of typical Rh(I)-catalysed reactions, such as the C–H borylation of arenes and cycloaddition of alkynes, to challenging substrates under blue light-emitting diode irradiation at room temperature.Ĭheung, K. The SFI-Rh(I) complexes with non-fused but π-extended ligands reduce substrate dependence owing to high visible-light-harvesting ability, and show high stability due to resistance against protonation. Here we report the design, synthesis and visible-light-induced non-radical reactions of dual-functional Rh catalysts, spiro-fluorene-indenoindenyl (SFI)-Rh(I) complexes. Several non-radical catalytic reactions have been developed, but these reactions are substrate dependent owing to the low visible-light-harvesting ability of the catalysts. However, most visible-light-driven catalytic reactions proceed via radical mechanisms, limiting the reaction types to which the catalysts are applicable. Such single-catalyst systems perform the dual function of visible light absorption and chemical transformation. Transition metal photo-induced catalysts operating in a single catalytic cycle are preferable compared with binary catalytic systems comprising both transition metal and photoredox catalysts.
0 Comments
There’s just a few things you’ll want to look out for while you’re here, which is why I’ve pulled this out as a separate phase. In this second phase of our Secret of Mana Trophy Guide there’s another handful of boss trophies to acquire, but you’re actually getting close to the end of the game if you’ve made it this far. It would be wise to only replace that backup save each time you’ve successfully collected some of the missable items below. Past this point, if you are not careful, the missable trophies will start to require a second playthrough, which we want to avoid. Now that you’re in the Underground City, create a backup save here which you can use at any time to return if needed. Phase Two – Rare Loot Farming in The Underground City, The Grand Palace & The Pure Lands You will get the same amount of exp regardless of which spell you use or how many allies/enemies you use it on, so try to use low-MP-cost spells when level-grinding your magic.Īfter defeating Aegagropilon at the end of Phase One of our Secret of Mana Trophy Guide, the following will happen: I recommend taking frequent breaks to increase these levels as it will help a lot with bosses and you’ll avoid a long all-at-once grind. For example, after activating 2 Mana Seeds, all Elemental spells can be increased to Level 2. The level cap will increase for each Mana Seed you activate. You can check their Magic Level from the Ally Wheel. To do so, you will need to use their spells as much as possible, gaining magic exp and leveling up their spells in the background.
![]() During exposure, most of the time a semi-transparent foil is placed above the plate+film+glas stack, but on the last minute or so this is retracted. The exposure unit has a high-power UV source, about 1 to 1.5 meters above the plate surface. Normally there is large, empty carrier film, on which the different typeset or raster-image films are mounted (using clear spray adhesive). Just look at, for example, how the printing plates in offset printing are exposed. Probably not really important here, but be aware that using diffused light, as well as as semi-transparent films, will also cast slight shadows. Using quartz glass is preferred, if possible. Oh, and about the glas: be aware that most normal glasses tend to filter UV light to some extent, requiring a longer exposure time. The lines will get thicker (and the spacing thinner) in the areas between the tubes, and will be the same widths directly above the tubes. Stack a second film on top of it, and the result will be less even. Using a single film, where the printed side is in contact with the photosensitive coating of the PCB, will produce a quite even result. For example, 10 mil lines spaced 10 mil apart, running in the same direction as the UV tubes. ![]() You can test this easily by exposing the PCB with a simple pattern of thin lines. This in turn will cast shadows at those places where the light hits at an angle. Since the paper/film is not infinitely thin, the second sheet will always be at a distance (the thickness of the first sheet) from the photosensitive coating. ![]() Everywhere else the light will hit at an angle. There you will have only four places where the light goes straight from the tube to the PCB: right above the tubes. Take a bog standard exposure box that uses four UV tubes, for example. However, pretty much everyone at home uses a small (read: thin) exposure box or similar, where the light sources are rather close to the board. If you use two films stacked on top of each other, this will cast shadows, unless you use a real point source for the UV light that is really far away. There should always be a glass there anyways, and some pressure applied (or a vacuum used) so that the film is in contact with the PCB. to check "real world" plugin usage during plugin development (i.e.complex automate integration tests (check various configurations before a release, see run-tests.sh script).The purpose of an example application is: HotswapAgent adds watchResources configuration.HotswapAgent extraClasspath is similar to JRebel configuration.You need a special IDE plugin to fix debugging. JRebel modifies bytecode of all classes on reload.JRebel is neither open source nor free.JRebel is currently more mature and contains more plugins.HotswapAgent does not need any additional configuration for basic project setup.HotswapAgent (DCEVM) supports Java8, Java11 and Java17!.Should you have any problems or questions, ask at HotswapAgent forum. Fast - until the plugin is initialized, it does not consume any resources or slow down the application (see Runtime overhead for more information).Framework support - through plugin-system, many frameworks are supported.Other resources like src/main/resources? Use watchResources property to add any directory to watch for a resource change. Reload resource after a change - resources from the webapp directory are usually reloaded by the application server.Extra classpath - Need change a runtime class inside dependent JAR? Use extraClasspath property to add any directory. ![]()
![]() Go to Settings, click on Server Settings, then select Advanced.In the Folder pane, look for IMAP mail and do a right-click.The removal of the email account will not affect your emails on the server. If the paths are set up accordingly, the other alternative is to delete the mail account within Windows Live Mail and recreate the email account from scratch. Make sure to enter them exactly, as shown above. Please note that the values for Sent, Drafts, and Trash are case-sensitive. Ensure that the boxes for Check new messages in all folders and Store special folders on the IMAP server are checked.Enter Inbox in the Root folder path field. ![]()
The layout used a unique shape but it is nice to know that this one has walk-in closets and wardrobe spaces for every bedroom. You can see that there is a partition between the dining area and living area. It is interesting to note that this floor plan doesn’t just have a parking area but also a pathway that is covered with pavers. Love that it has an outdoor space where one can enjoy the views and enjoy dining time as well. You can see so many colors in this layout and so many plants as well that it almost looked tropical to me. Because of the stairs that you can see here, you can tell that this apartment is located on an upper floor. CH 3 Bedroom 2nd Floor PlanĪ simple square shaped floor plan wherein it has a small porch that can be accessed through French doors. It appears that there would be a long line at shower time because there are about six people living here with only two bathrooms. This one has two bathrooms with five beds. I just don’t like that hallway that looks boxed in. Aside from the garage for two cars, it also has an outdoor dining area, a laundry area and built-in wardrobes for each room. I wonder why there is a partition in the outdoor space which I think is not necessary. You can see that the house is elevated with a spacious balcony. Isn’t this stunning? I love all the colors of this floor plan. It also features a laundry area that can be accessed from the kitchen. Three Bedroom, Three BathroomĪside from three bedrooms, this one also has three bathrooms as well. In its public area, it used an open floor plan with wooden flooring. What I noticed here are the folding glass doors that are used to connect the different areas of the house. It might not be too spacious but it does have everything one needs to live. So, if you have two cars and you live in a one-storey home or apartment, then this layout is good for you. Just a simple design of a home interior which has two porches that can be accessed through the bedrooms. In the masters bedroom, there is an ensuite bathroom too and a walk-in closet. It has a spacious living and dining area. This incredible floor plan will make life convenient giving you more time to relax and enjoy comfortable living. There is also a fully-equipped kitchen with granite countertops, sleek silver appliance package, stylish tile backsplash, and under mount sinks with gooseneck faucets. It features faux wood flooring, 2-inch plantation blinds, and the upscale brushed nickel hardware and lighting package. This floor plan will make you fall in love with its comfortable and spacious three bedroom apartment home which provides the distinct and unique look you deserve. Three Bedroom: 3 Bedroom/2 Bath- 1320 sq. Notice that there are many built-in cabinets and closets in this apartment. If you want something that is simple with neutral colors in it, this could be perfect for you. I love the colors used here as well as the wooden flooring in the bedrooms. This layout makes space for a living area including a TV room so the homeowners can have a nice quiet time when necessary. This three bedroom apartment is ideal for entertaining. This one features a wide open outdoor area and also a cozy dining room. Let us scroll down and take a look at the layouts and choose one that works well for you. We have collated 20 of these floor plans for spaces that have three bedrooms. It is actually tough to find these 3D floor plans but don’t worry because we got you covered. You can also take inspiration on how you will decorate it through beautiful modern home plans. ![]() By using 3D floor plans, you will be given ideas on how you can combine various items together in a space. Using 3D floor plans could be helpful for you whether you’re moving into a new house, building a new one, or are just looking for an inspiration on how to arrange the place that you live in. So, today, we are going to give you a list of 3D apartment or one-storey three bedroom floor plans to give you ideas on how you could do the layout of your spaces. Good if you only have an open layout and you let the furniture define the spaces but it would be a different story if you are adding permanent structures or features. You do not want to make the mistake of choosing a certain layout that actually doesn’t work because it would be hard to do it again especially if you are installing dry walls. Sometimes, it is really challenging to arrange an interior no matter how big or how small is the available space. This research identified seven key dimensions of inclusion: fair treatment, integrating differences, decision-making, psychological safety, trust, belonging, and diversity. Gartner set out to address this challenge by building a model of inclusion based on qualitative interviews with more than 30 DEI executives and an extensive review of the academic literature and existing indices. The challenge, however, is in first establishing the right metrics and then asking the right questions. ![]() Many organizations are still navigating a relatively new hybrid work environment as well.Įmployee feedback is also the most useful data source for measuring inclusion, especially when leaders can use a “pulse,” a quick survey, to check in with employees without adding to distractions. As employees react to disruptions at work, at home, and in the world around them, feelings and opinions can change faster than an annual engagement survey can detect. ![]() In today’s uncertain and rapidly changing work environment, employee feedback is an important input to any talent decision. Capturing Employee Perceptions of Inclusion New Gartner research outlines how to put numbers to the concept, what meaningful action looks like from leaders, and potential pitfalls to avoid in the process. To effectively track inclusion, organizations must measure employee sentiment with a considered definition of inclusion, ensuring the organization can act fast on the results. This shortcoming has obstructed efforts to develop a unified and coherent metric that tracks overall DEI progress over time. But although organizations have found ways to successfully measure and track diversity, they haven’t been able to do the same for inclusion. Most leaders understand that it is inclusion that unlocks the potential in a diverse workforce. Even once you have that demographic information, it’s hard to know what mark you’re trying to hit: What does “good” look like, in terms of representation?īut inclusion, and a work environment where all people feel respected, accepted, supported and valued, allowing all employees to fully participate in decision-making processes and development opportunities within an organization, is even more of a challenge to measure. ![]() While a recent Gartner survey reveals DEI leaders indicated that “setting goals and tracking DEI progress through metrics” was one of their two top priorities for 2021, measuring workforce representation is a challenge unto itself, particularly for global organizations that need to manage self-identification and define their underrepresented talent segments across geographies. ![]() Gartner analysis reveals an almost 800% increase in job postings for dedicated diversity recruiters. According to Gartner research, the number of HR leaders identifying DEI efforts as a top priority was 1.8 times higher in 2020 than in 2019. More than 1,600 CEOs have signed onto the CEO Action for Diversity & Inclusion Pledge, and 40% of companies discussed diversity and inclusion in their Q2 2020 earnings calls versus only 4% the same quarter a year prior. Unfortunately, many organizations still struggle to measure the impact of their strategies and communicate that impact to a growing number of stakeholders. There’s no doubt that in 2021 and beyond, companies will continue to devote more attention and resources to advancing diversity, equity, and inclusion (DEI). ![]() To keep the delicate 'fit from falling, dainty silk straps were added across the shoulders, crisscrossing at the top of Addison's back. ![]() Seen in the second pic of her Instagram dump, the body-hugging, black jumpsuit featured an intricate floral lace pattern, adding a girly flair to the edgy design. Taking a break from posing, Addison sat down on the studio floors wearing this absolute stunner of a dress. Case in point - her recent super sheer, black ensemble.įor a recent cover shoot with Remix Magazine, Addison proved that she is *the* moment in a slinky, low-back catsuit that was completely sheer. We only know this thanks to fashion fan account theaddisoneasterlingcloset, who sourced Addison's bikini as being the Clover Top and Clover Bottom from Knight Swim. As we transition to fall (!!), we can expect Addison to keep us lookin' drippy. Today in Addison Rae bikini hacks, the He's All That star appears to have worn her bikini bottoms backwards earlier this summer. If you needed bikini inspiration this season, Addison was your go-to girlie, with her wardrobe including mismatched two-pieces, plenty of patterns, and sheeny, teeny thongkinis. The 21-year-old content creator has been keeping the temps high all summer, serving punk-pop in a handkerchief dress, globetrotting gal with Omer Fedi in Italy, and pilates princess not once, not twice, but thrice. And let us just say, her sheer, lingerie-inspired one-piece is truly a showstopper. She has given us one heck of a wake-up call with the most *amazing* behind-the-scenes look at her recent photoshoot. Good morning to Addison, and Addison only. What do all these words have in common? Why, Addison Rae, ofc! Her sheer, lingerie-inspired one-piece is truly a showstopper.Īddison proved that she is *the* moment in a slinky, low-back catsuit that was completely sheer. "Hearst Magazines and Yahoo may earn commission or revenue on some items through the links below."Īddison Rae gave a behind-the-scenes look at her recent photoshoot. ![]() The story takes place in a world called "Ivalice," in an age when magic was commonplace and airships plied the skies - the Archadian Empire, seeking to strengthen its base of power, had been invading and subjugating its neighboring lands one by one- a fate which befell the small Kingdom of Dalmasca. The violent world of Greek mythology comes to life in gory detail as Kratos encounters new mythical characters, and compete in epic boss battles in his quest. ![]() The journey takes them through vividly striking environments where they are faced with a labyrinth of challenging puzzles and mini-games intricately woven into the story. Armed with the deadly blades and blistering rage, players are aided by new breath-taking magic and new brutal combat moves. In God of War II, players retake the role of Kratos. God of War II sets an epic stage for a devastating mythological war to end all wars. To end his continued torment, Kratos must journey to the far reaches of the earth and defeat untold horrors and alter that which no mortal, or god has ever changed, his fate. In God of War II, Kratos sits atop his Olympus throne, as the new God of War – far more ruthless than Ares ever was. God of War saw Kratos, a mortal warrior, set upon an epic quest to dethrone a God. Continuing the dynasty: Project the season's top performers with the new Pre-Season All-American Team and revel in your weekly accomplishments with new Sports Illustrated magazine covers. Over 150 new teams: Play as one of 36 new 1-AA teams or one of the 100+ NEW Classic Teams including 1930 Notre Dame, 1956 Oklahoma, 1972 USC, 1985 Auburn, and 2002 Ohio State. Take over the game at a key situation, relive the glorious victory, or change history with an upset. New College Classics mode: Replay 20 of the greatest college football games from the last two decades. See the receivers better through a new QB Rollout camera and use the Play-Action Pass camera to fake out the defense. New animations include sideline tackles, stumbles, new over-the-shoulder and basket catches, user-controlled celebrations, and much more. ![]() Get in the end zone with new trick plays like the Halfback Throwback and Wide Receiver Double Reverse Pass. Chat or sing your favorite fight song in-game with EA SPORTS Talk, or follow the stat leaders across the country in the Online Top 100. Nebraska, and more in online head-to-head exhibition games. Take the rivalry online: Battle Michigan vs. For those that need that sense of freedom and escape, why not charter a helicopter and see the beauty of Vice City from the air? For the sportsman, a powerboat or a golf buggy lets you enjoy the great outdoors. For the speed enthusiast, there's high-performance cars and motorbikes. Vice City offers vehicular pleasures to suit every taste. His only answer is to fight back and take over the city himself. Most of Vice City seems to want Tommy dead. Sonny wants his money back, but the biker gangs, Cuban gangsters, and corrupt politicians stand in his way. He's set up and is left with no money and no merchandise. But all does not go smoothly upon his arrival in the glamorous, hedonistic metropolis of Vice City. They were understandably nervous about his re-appearance in Liberty City, so a trip down south seemed like a good idea. Having just made it back onto the streets of Liberty City after a long stretch in maximum security, Tommy Vercetti is sent to Vice City by his old boss, Sonny Forelli. ![]() With several market expansions over the years, the multi-city festival has amassed a loyal following with over 60,000 in attendance in 2021 in Ohio, North Carolina, and Michigan. The Breakaway Music Festival began in Columbus, OH, in 2013 and quickly grew into a two-day, multiple stage festival bringing exceptional names like Chance The Rapper and Kendrick Lamar to the Midwest. ![]() ![]() The west coast Breakaway will feature live music from Gryffin, Louis The Child, Big Wild, Said The Sky, Tycho and more. Set for Friday, October 14 & Saturday, October 15, Breakaway Music Festival is debuting in the Bay Area at the Bill Graham Civic Auditorium in San Francisco, CA. We’re not just an EDM festival, we’re more of a contemporary festival with whatever is really trending in music.”Įxplore the lineups below and get tickets to Breakaway Music Festival in your area here.Breakaway Music Festival - Bay Area Bill Graham Civic Auditorium | October 14 - 15 “We love the idea that we’re not strictly a one-genre festival,” Lynn shares. Also, Swae Lee, Two Friends, Wax Motif, Gryffin, Lane 8, Trevor Daniel and more.Īs mentioned, Breakaway’s concept brings people from different areas and with various musical tastes together. Breakaway Music Festival returned in 2021 with four destination events in Cancun, Michigan, Ohio and North Carolina, with plans to bring the Breakaway experience to more new markets in 2022. Plus, Chelsea Cutler, Gryffin, 24KGOLDN, Madeon, Sofi Tukker, Channel Tres, Elderbrook, John Summit, Sonny Fodera, Two Feet, Alexander 23, Bonnie x Clyde, Sam Feldt, Sidepiece and more.īreakaway North Carolina, taking over Charlotte Motor Speedway on October 1 & 2, features yet another impressive lineup of acts with Martin Garrix, G-Eazy, and The Chainsmokers leading the pack. The festival amassed a loyal following with over 65,000 in attendance in 2019 in Ohio, Tennessee, North Carolina, and Michigan. Next month, Breakaway Ohio is set to take place at Historic Crew Stadium over September 3 & 4, featuring Kygo and Illenium on headlining duties. That happened with Louis the Child and a ton of different acts where we’ve been able to help elevate their career through the Breakaway platform.” ![]() Being able to share that experience firsthand with these artists - where they go from the opener to the headliner. Lynn lists Michigan’s own Quinn XCII as a major highlight, “He started off as one of the opening acts for the festival and now he’s headlining his own day. The lineup also includes Gryffin, Big Wild, Chelsea Cutler, Madeon, Loud Luxury, Dion Timmer, Frank Walker, Gettoblaster, Elderbrook, Alexander 23, Drummxnd and DŸLAN. This weekend, Breakaway Michigan returns to Belknap Park in Grand Rapids over August 27 & 28 with two major headliners, EDM sensation Illenium and acclaimed singer-songwriter Quinn XCII. That was the thesis of Breakaway and now we’ve scaled to a lot more cities.” “That’s why we love being in places like Columbus and Grand Rapids, bringing what we think is a true festival experience to smaller markets in people’s backyards. “One of the things we like to do is bring really awesome experiences to secondary markets,” Lynn explains. This year, Breakaway has curated three unique lineups for Grand Rapids in August, Columbus in September, and Charlotte in October. Tickets for the two-day event go on sale Thursday, July 21st at 10 am PST via Ticketmaster. Breakaway is a fast-growing, multi-city music festival, focusing on events for all ages across the midwest including Ohio, Michigan, The Carolinas and Tennessee. Set for Friday, October 14th and Saturday, October 15th at Oakland Arena Grounds in Oakland, Northern California, the west coast Breakaway will feature live music from Gryffin, Louis The Child, Big Wild, Said The Sky, Tycho and more. |